Promotion of oxygen atom transfer in Mo and W enzymes by bicyclic forms of the pterin cofactor.
Chem Commun (London) (2005) PMID 15724177
Density functional theory calculations suggest that bicyclic structures of the "molybdopterin" in DMSO reductases may have an important catalytic role in oxygen atom transfer reactions.
DOI: 10.1039/b415480k
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