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Analysis of trimethyl carboxyphosphate by gas chromatography-mass spectrometry

Matthew J McIldowie, Paul V Attwood, Anthony Reeder, and Matthew J Piggott

Anal Biochem 376(2):3 (2008) PMID 18294947

Analysis of trimethyl carboxyphosphate samples by gas chromatography-mass spectrometry, using typical conditions resulted in significant decomposition of the analyte. Optimization of injection conditions, including conditioning of the injection port liner, produced a dramatic increase in observed peak areas and afforded an effective method for detection of trimethyl carboxyphosphate at the <1@mg mL^-^1 level.

Copyright © 2008 Elsevier Ltd. All rights reserved.

DOI: 10.1016/j.ab.2008.01.027
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