Triphenylamine/tetracyanobutadiene-based D-A-D π-conjugated systems as molecular donors for organic solar cells.
Org Lett 13(12):3098-101 (2011) PMID 21595459
Thiophene-based D-A-D π-conjugated systems containing triphenylamine end groups connected to a 1,1,4,4-tetracyanobuta-1,3-diene acceptor by oligothiophene chains of variable length have been synthesized. These compounds show interesting light-harvesting properties and low-lying HOMO levels. Preliminary results on bilayer heterojunction solar cells with C(60) as acceptor show power conversion efficiency higher than 1.0%.
DOI: 10.1021/ol201002j
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