Ligand effects on the stability of thiol-stabilized gold nanoclusters: Au(25)(SR)(18)(-), Au(38)(SR)(24), and Au(102)(SR)(44).
We have studied the electrochemical and thermodynamic stability of Au(25)(SR)(18)(-), Au(38)(SR)(24), and Au(102)(SR)(44), R = CH(3), C(6)H(13), CH(2)CH(2)Ph, Ph, PhF, and PhCOOH, in order to examine ligand effects on the stability of thiol-stabilized gold nanoclusters, Au(m)(SR)(n). Aliphatic thiol...