Latest papers

Monoiron hydrogenase catalysis: hydrogen activation with the formation of a dihydrogen, Fe-H(delta-)...H(delta+)-O, bond and methenyl-H4MPT+ triggered hydride transfer.

Biomimetic Model Featuring the NH Proton and Bridging Hydride Related to a Proposed Intermediate in Enzymatic H 2 Production by Fe-Only Hydrogenase

Hydrogen Activation by Biomimetic Diiron Dithiolates

Unveiling how stereoelectronic factors affect kinetics and thermodynamics of protonation regiochemistry in [FeFe] hydrogenase synthetic models: a DFT investigation.

Theoretical Study of Dioxygen Induced Inhibition of [FeFe]-Hydrogenase

DFT/TDDFT exploration of the potential energy surfaces of the ground state and excited states of Fe2(S2C3H6)(CO)6: a simple functional model of the [FeFe] hydrogenase active site.

Fluorophenyl-substituted Fe-only hydrogenases active site ADT models: different electrocatalytic process for proton reduction in HOAc and HBF4/Et2O.

A dithiolate-bridged (CN)2(CO)Fe-Ni complex reproducing the IR bands of [NiFe] hydrogenase.

An autocatalytic mechanism for NiFe-hydrogenase: reduction to Ni(I) followed by oxidative addition.

Catalytic electrochemistry of a [NiFeSe]-hydrogenase on TiO2 and demonstration of its suitability for visible-light driven H2 production.

Spin distribution of the H-cluster in the H(ox)-CO state of the [FeFe] hydrogenase from Desulfovibrio desulfuricans: HYSCORE and ENDOR study of (14)N and (13)C nuclear interactions.

Hydrogen photoproduction by use of photosynthetic organisms and biomimetic systems.

Electron-transfer subunits of the NiFe hydrogenases in Thiocapsa roseopersicina BBS

Diversity and transcription of proteases involved in the maturation of hydrogenases in Nostoc punctiforme ATCC 29133 and Nostoc sp. strain PCC 7120.

Unusual formation of a [NiSFe2(CO)6] cluster: a structural model for the inactive form of [NiFe] hydrogenase

Transcription profiles of hydrogenases related genes in the cyanobacterium Lyngbya majuscula CCAP 1446/4.

Genome analysis and genome-wide proteomics of Thermococcus gammatolerans, the most radioresistant organism known amongst the Archaea.

Effect of tungsten and molybdenum on growth of a syntrophic coculture of Syntrophobacter fumaroxidans and Methanospirillum hungatei.

Electronic structure of a binuclear nickel complex of relevance to [NiFe] hydrogenase.

Aza- and oxadithiolates are probable proton relays in functional models for the [FeFe]-hydrogenases.