Latest papers

Reaction of N-vinylic phosphazenes with alpha,beta-unsaturated aldehydes. Azatriene-mediated synthesis of dihydropyridines and pyridines derived from beta-amino acids.

Synthesis and characterization of biocompatible poly(organophosphazenes) aiming for local delivery of protein drugs.

Biologically relevant phosphoranes: structural characterization of glucofuranose- and xylofuranose-based phosphoranes.

Three-component reaction between triphenylphosphine, dialkyl acetylenedicarboxylates and urea or N-methylurea.

Iminophosphorane-mediated efficient synthesis of new tricyclic 3,5-dihydro-1,2,3-triazolo[4,5-d]-1,2,4-triazolo[1,5-a]pyrimidin-9-ones.

31P NMR chemical shifts in hypervalent oxyphosphoranes and polymeric orthophosphates.

Synthesis of potential purinoceptor antagonists: application of P1-tBU phosphazene base for alkylation of adenine in solution and on solid phase.

Chiral separation and CD characterisation of enantiomeric cyclotriphosphazene derivatives.

Biologically relevant phosphoranes: structural characterization of a nucleotidyl phosphorane.

Preparation of ketones from nitriles and phosphoranes.

Saturation transfer and chemical exchange measurements of the stereochemical drift occurring during the Wittig reaction.

Synthesis, characteristics and biological activity of pentacoordinated spirophosphoranes derived from amino acids.

Smooth solvation method for d-orbital semiempirical calculations of biological reactions. 1. Implementation.

Chemical confirmation of a pentavalent phosphorane in complex with beta-phosphoglucomutase.

Pseudorotation barriers of biological oxyphosphoranes: a challenge for simulations of ribozyme catalysis.

Structure and binding of Mg(II) ions and di-metal bridge complexes with biological phosphates and phosphoranes.

Guanidinium groups act as general-acid catalysts in phosphoryl transfer reactions: a two-proton inventory on a model system.

Compelling evidence for a stepwise mechanism of the alkaline cyclisation of uridine 3'-phosphate esters.

Pseudorotation of natural and chemically modified biological phosphoranes: implications for RNA catalysis.

Convenient solid-phase synthesis of oligopeptides using pentacoordinated phosphoranes with amino acid residue as building blocks.